In a large skillet over medium heat, melt the butter.
Scatter 1 cup butterscotch chips in a single layer over the butter, and remove pan from heat. Do not stir. Set aside.
Meanwhile, in a large bowl, combine flour, brown sugar, baking powder, and salt.
Add vanilla, eggs, and butterscotch chip mixture to the dry ingredients, stirring until combined. The butterscotch chips will be quite melted, and will easily incorporate into the batter.
Fold in remaining butterscotch chips and pecans.
Line a 13x9-inch pan with foil, allowing it to hang over the edges.
Spray lightly with non-stick spray.
Spread batter into prepared pan.
Bake at 325 degrees for 25-30 minutes, or until edges are golden brown, and a toothpick inserted near the center comes out clean.
Remove pan to a wire rack to cool completely.
Lift the blondies by the foil edges to remove from pan.